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7 is Fanny Blankerskoen (no idea on the correct spelling).

Pretty much every episode they define country as "and by country we mean a sovereign state that is a member of the UN in its own right", so as the Vatican is not a member of the UN it does not meet their definition. I don't know what definition they used, if any, for this quiz as I didn't go...

It wouldn't count as a nation on Pointless.

Think 8 might be Vienna and Bratislava.