Having had a play around, this sounds like the best/easiest way.
May have a look at Dropbox in the future for documents but iCloud sounds fine at the moment for pictures of the Missus dressing up our dog etc.
Thanks for your help and ideas everyone, much appreciated.
Cheers guys, the Missus is updating (iPhone 4) to iOs 7 now so we'll have a look at Airdrop.
If that doesn't work out, Dropbox seems the way forward as the photos will also go on the laptop.
All this cash spunked on Apple devices but barely get £20 use out of them!
Between 2 of us. We have an iPhone 4, iPhone 5S and a Windows laptop.
Is there anyway we can sync or send photos easily between our phones or to the laptop?
All we're doing at the moment is sending emails from the phones (with attachments) which are then picked up on the laptop, but it'd be so...